Ultracentrifuge experiment on AgI super-ionic conductor

Ono, Masao; Okayasu, Satoru; Iguchi, Yusuke*; Esaka, Fumitaka; Bagum, R.*; Haruki, Rie; Mashimo, Tsutomu*

Transactions of the Japan Society for Aeronautical and Space Sciences, Aerospace Technology Japan (Internet), 12(ists29), p.Tq_1 - Tq_3, 2014/04

https://doi.org/10.2322/tastj.12.Tq_1

We had realized the composition gradient of elements or isotopes in some binary alloys or single element by solid-state centrifugation. While, it might difficult to realize graded structure of elements in binary ionic crystal by centrifugation as it strongly keeps their stoichiometry. However, isotope fractionation in binary ionic crystal by centrifugation might be expected as the self-diffusion of ions occurs. We have planed the ultracentrifuge experiments on -AgI superionic conductor to investigate the isotope effect in binary ionic crystal under a strong centrifugal acceleration field. -AgI superionic conductor is suitable for the confirmation experiment as it is an intrinsic ionic crystal and Ag ions have high diffusivity. For the first stage, we have experimentally searched the experimental conditions of magnitude of centrifugal acceleration and temperature that ensure the experiment without decomposition. It is confirmed that the combination of experimental conditions of up to 6.110 g, 350C, 24h ensure the experiment without decomposition at least.